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That's a pretty one!
I've seen it in the little blue book a few years ago and I think it was over 2000.00.
You might give them a call and ask. I think it was called the diamond flower ring.
I've never seen it before but it looks similar to something from the victoria collection. Also I don't see a Tiffany hallmark on the inside of the band which should be on every one of their pieces. Can you ask him to send you a pic of the hallmark?
I think it's either from the Victoria collection or not part of a collection. Diamond flower ring sounds like something of theirs.