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The only solution I have found to this problem is the following.
Apply a strong anti-perspirant such as Certain-Dri or Maxim every night, as directed.
Note: Regular anti-perspirant products won't work well as they are not strong enough.
In the morning, shower, and don't apply more anti-perspirant. The previous night's Certain-Dri or Maxim application will be sufficient, even if you wash well with soap (as you should!). Instead, use a regular deodorant (without antiperspirant) after showering. It's the aluminum and other chemicals in anti-perspirant that cause the yellow staining--those things are NOT an ingredient in regular deodorant--so this regimen will ensure that your light clothes don't get stained. I recommend some of the natural deodorant options, like Tom's of Maine, as they contain some non-staining ingredients that fight bacterial growth, supposedly.
You'll need a few days for the Certain-Dri or Maxim to start working well, so give it a chance. It may irritate those with sensitive skin, so apply a thin but comprehensive layer... but don't saturate or go crazy with the application.
This method has worked for me and, for the first time in years, I have not tossed out clothes for reasons of yellow armpit staining. You also can feel confident about not sweating OR smelling bad. The nightly application of Certain-Dri or Maxim will take care of that!
Nukleopatra
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