There are also never-before-seen items worn by Madonna off-stage.
A favourite cap from her time at the University of Michigan, bearing Madonna's signature on the peak; a set of pearl bracelets and necklaces she wore throughout the Eighties.
One of the more personal exhibits is a gold and emerald cross given to Madonna by James Albright, who worked as a security guard for the star in 1992.
She is currently embroiled in a legal battle with Albright over his decision to make public love letters she apparently wrote to him during their relationship, but in happier times, the pair dated for two years, when Albright had the bespoke cross, crafted in gold with six emeralds, designed for Madonna.
There's other, more diverse paraphernalia too.
A personal cheque for $129.05 signed by Madonna Ciccone and made out to beautician Simone Sable for the singer's waxing appointment.
A first edition of one of Madonna's self-penned children's books, Lotsa de Casha, signed "Love Madonna, and a signed first edition of Madonna's first children's book, The English Roses.
This collection represents every stage of her glittering career," says curator Ted Owen.
"These are museum-quality pieces - but they will be presented in keeping with the glamour and sense of theatre that the queen of pop has made her trademark - and Madonna fans should be very excited indeed."
Madonna fan and expert James Harknett will add to the exhibition with items from his own vast collection of Madonna memorabilia, including costumes and props from Evita, promotional material from around the globe, magazines, store displays and posters.
The exhibition, Owen says, is an unprecedented collection of Madonna memorabilia.
Simply Madonna: Materials of the Girl. the world's largest collection of Madonna's stage and film costumes and artefacts.
Old Truman Brewery, London. 21 February - 22 March 2009
There are more pictures of Madonna's things in the article:
http://www.dailymail.co.uk/femail/ar...ssessions.html
Left, a signed page from a first edition copy of Madonna's first children's book, The English Roses. Right, a signed page from a first edition copy of Madonna's children's book Lotsa de Casha